Technical knowledge
Duplex 2205 flanges to ASTM A182 F51: what the grade actually delivers
Duplex 2205 flanges to ASTM A182 F51 and UNS S32205: composition, strength advantage over 316L, temperature limits, sigma phase risk and what to state on the purchase order.

Why the two phase structure matters
Duplex stainless steel contains roughly equal amounts of ferrite and austenite. The ferrite phase provides strength and chloride stress corrosion cracking resistance, while the austenite phase provides toughness and ductility. This combination is what allows a 2205 flange to be both thinner and more corrosion resistant than its 316L equivalent.
Composition and mechanical properties
| Item | Value | Significance |
|---|---|---|
| UNS number | S31803 or S32205 | S32205 is the tighter, preferred range |
| Chromium | 21.0 - 23.0 % | Passivity, pitting resistance |
| Nickel | 4.5 - 6.5 % | Austenite balance |
| Molybdenum | 2.5 - 3.5 % | Pitting and crevice |
| Nitrogen | 0.08 - 0.20 % | Strength, PREN, weld restoration |
| Yield strength | About 450 MPa | Roughly double 316L |
| Typical PREN | 35 - 38 | Well above 316L |
| Recommended metal temperature | About minus 50 to 300 C | Upper limit set by phase stability |
S31803 or S32205: specify the tighter range
The two UNS numbers cover similar alloys but S32205 has narrower chromium, molybdenum and nitrogen ranges that keep the composition inside the window where pitting resistance is reliable. Most modern project specifications call for S32205 and require the pitting resistance equivalent number to be calculated and reported for each heat.
Heat treatment and inspection requirements
- Solution anneal and quench. Typically around 1020 to 1100 C followed by water quench. Slow cooling through the 600 to 900 C range precipitates sigma phase.
- Ferrite measurement. Where specified, verify the ferrite content of the forging and of the weld metal.
- Impact testing. Often required at minus 46 C for offshore and subsea service.
- Weld procedure. Use a nitrogen bearing over alloyed filler such as ER2209, control interpass temperature, and avoid excessive heat input.
Questions about this topic
Can duplex 2205 replace 316L directly?
What is the maximum temperature for duplex 2205?
Is duplex magnetic?
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