Technical knowledge
Inconel 690 for steam generator tubing and caustic service
Why Inconel 690 replaced Inconel 600 in steam generator tubing: stress corrosion cracking resistance, chromium content, thermal treatment and specification notes for seamless tube and fittings.

Why the industry moved from 600 to 690
Inconel 600 tubing gave decades of service before operators began seeing primary water stress corrosion cracking and outside diameter stress corrosion cracking in the crevices of tube support plates. Laboratory and plant data showed that raising chromium from about 15 % to about 30 % increased the time to cracking by more than an order of magnitude, which led to the widespread adoption of 690 for replacement generators and retubing campaigns.
Composition and the thermal treatment that matters
| Item | Inconel 600 | Inconel 690 |
|---|---|---|
| UNS number | N06600 | N06690 |
| Chromium | 14.0 - 17.0 % | 27.0 - 31.0 % |
| Nickel plus cobalt | 72 % minimum | 58 % minimum |
| Iron | 6.0 - 10.0 % | 7.0 - 11.0 % |
| SCC resistance in primary water | Susceptible | Very high |
| Typical specification | ASTM B163 / B167 | ASTM B163 / B167, SB-163 |
Tip Specify thermal treatment explicitly. Mill annealed 690 tubing performs differently from tubing given a thermal treatment that develops semicontinuous grain boundary carbides, and that treatment is a recognised requirement for steam generator tubing.
Beyond steam generators: caustic and nitric service
- Caustic evaporators. 690 resists caustic stress corrosion cracking better than 600 at high concentration and temperature.
- Nitric acid service. The high chromium content gives excellent resistance to oxidising acids where molybdenum bearing alloys are not needed.
- Waste incineration and flue gas treatment. Useful where both oxidising salts and chlorides are present.
Buying notes for tube and fittings
Order seamless tube to ASTM B163 or B167 as applicable and butt weld fittings in the same UNS number so the weld metal and parent metal share a corrosion mechanism. Require the certificate to quote actual chromium and carbon values, the thermal treatment temperature and time, grain size where specified, and the results of intergranular attack testing when the purchase specification calls for it.
Questions about this topic
Is Inconel 690 always better than 600?
Can 690 be welded with 600 filler metal?
What is thermal treatment in this context?
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