Technical knowledge
Incoloy 825 for sulphuric and phosphoric acid piping
Incoloy 825 composition, acid resistance, temperature limits and specification notes for flanges, fittings and seamless tube in sulphuric, phosphoric and sour produced water service.

Why 825 sits where it does in the price and performance ladder
Incoloy 825 was designed as an iron nickel chromium alloy with deliberate additions of molybdenum, copper and titanium. The nickel level removes chloride stress corrosion cracking, the molybdenum handles pitting, the copper helps in reducing acids such as sulphuric, and titanium stabilises the structure against sensitisation so welded components do not lose intergranular resistance.
Composition and properties
| Element | Range | Contribution |
|---|---|---|
| Nickel | 38.0 - 46.0 % | Chloride stress corrosion cracking resistance |
| Chromium | 19.5 - 23.5 % | Oxidising acid and passivity |
| Molybdenum | 2.5 - 3.5 % | Pitting and crevice resistance |
| Copper | 1.5 - 3.0 % | Reducing acid performance |
| Titanium | 0.6 - 1.2 % | Stabilisation against sensitisation |
| Iron | 22 % minimum | Cost control |
| Typical PREN | 30 - 33 | Above 316L, below 625 |
Where it performs and where it does not
- Sulphuric acid up to about 40 % concentration. Copper plus molybdenum give useful resistance at moderate temperature; above that, move to a high molybdenum alloy.
- Phosphoric acid production. Widely used in evaporators and piping, though fluoride and chloride content can push the duty beyond 825.
- Sour produced water and gas. Listed in NACE MR0175 / ISO 15156 and commonly used for tubing, flanges and fittings.
- Seawater with moderate temperature. Acceptable in flowing, aerated conditions; stagnant warm seawater favours 625 or super duplex.
- Avoid strong hydrochloric acid. That is the territory of Hastelloy B-3 or C-276.
Specifying flanges, fittings and tube in 825
Order forged flanges to ASTM B564 and wrought butt weld fittings to ASTM B366, both to UNS N08825, with seamless tube to ASTM B423 or B163 as applicable. State the stabilising anneal, require positive material identification, and ask for the certificate to quote molybdenum and copper since those two elements decide performance in reducing acid and are the first thing to drift in a non conforming heat.
Questions about this topic
Is Incoloy 825 the same as Alloy 825?
Can 825 be used for hydrochloric acid?
Does 825 need post weld heat treatment?
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